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    过氧化氢催化分解反应速率常数的测定

    时间：2019-03-26    下载该word文档
    elationship between Government and business. The "two sessions", General Secretary of "Pro", "clear" the word succinctly summarized the new relationship between Government and business, as pure politics, reshaping the political relationship specified in the direction. District leaders in handling political and business relations, engage in trading power for money, and finally stumbled, we a lesson, always keep in mind that "Pro", "clean" practicing "Pro", "clear". "Pro" is to open a sincere engagement with private enterprise to help solve practical difficulties; " Clear "is to clarify the Division of power, exercised in accordance with, private entrepreneurs with innocent purity, not abusing power for personal gain, not to engage in trading power for money. Third, in order to maintain fairness and justice. Fairness and justice is the lifeline of the rule of law, is the best development environment. Currently, lax law enforcement and the judicial sector in our region also exist to varying degrees, lawenforcement departments and individual window units power for personal gains and bribes, thick friends, relations, human cases, money cases in which seriously infringe on the legitimate rights and interests of enterprises and people. Especially some law enforcement and inspection for profit purposes, deliberately looking for corporate loopholes, found directly under the ticket does not give business improvement opportunities. We recruit a company doesn't easily, cultivating a business more difficult, never for personal gain, systematic harassment, card, last checked to check to get the enterprise collapsed. o guarantee the legitimate rights and interests. Always proceed from the overall situation of reform and development of services, fully consider the characteristics of production and management in non-public enterprises and social benefits, an accurate grasp of legal limits, protect the enthusiasm of entrepreneurs and practitioners in innovation and entrepreneurship, enhancingexpectations and confidence. To promote strict enforcement. Strengthening law enforcement procedures, improve law enforcement performance evaluation, strengthening the supervision of law enforcement, exploration and practice of risk control mechanism of law enforcement to further standardize the social security, urban management, road traffic administrative law enforcement, effectively free, extensive law-enforcement and lax enforcement of law enforcement and other issues. o uphold justice. Justice is the last line of Defense to safeguard fairness and justice, to unequivocally support the courts and procuratorates independently exercise level ... Judicial activities were rampant, must not be allowed to run, favors, money, must not be allowed to knowingly violate the miscarriage, violations of the legitimate rights and interests of the masses must not be allowed to abuse of power, to make forest mass can be felt in every judicial cases in equity and justice. Four to deepen grass-roots governance according to law过氧化氢催化分解反应速率常数的测定
    一、实验目的
    （1）了解过氧化氢催化分解反应速率常数的测定方法。
    （2）熟悉一级反应的特点，了解催化剂对反映速率的影响。
    （3）掌握用图解计算法求反应速率常数。
     二、实验用品
    1、仪器
    玻璃反应容器1个、水准瓶1个、50mL量气管1个、超级恒温槽1套、三通活塞1个、秒表1块、10mL量筒1个、5mL吸量管2支、胶管3m。
    2、药品
    质量分数为2%的H2O2溶液（新鲜配制）、0.1mol·L-1KI溶液。
    三、实验原理与技术
    过氧化氢很不稳定，在常温下的分解反应式为：
    H2O2→H2O+1/2O2 （Ⅰ） 在KI作用下的分解反应机理为：
    H2O2+KI→KIO+ H2O （慢） （Ⅱ） KIO→KI+1/2O2 （快） （Ⅲ）
    rass-roots governance according to law is an important foundation for promoting the construction of rule of law, but also the most basic development environment. Despite my good social order in General, but there are law-abiding consciousness, social order is not standard, regardless of faith, Twining visit visit and other outstanding problems. We want to actively promote the field of multi-level governance according to law, promote the continuous improvement of the social environment. o promote universal compliance. Actively foster the rule of law culture, carry out law publicity and education on honesty and trustworthiness, guide the masses and consciously abide by the law, failing to find method, problem-solving method, method of gradually changing the world, he is not looking for but someone "unspoken rules", formed all law law, abide by the good atmosphere. To strengthen the comprehensive management of public security. Deepening peace xingan construction, stronglyagainst violence crime, mafia and serious criminal offences, to protect the legitimate rights and interests of citizens, legal persons, carry out criminal policy of temper justice with mercy, the maximum stimulating social vitality, and earnestly safeguard sociaharmony and stability. To resolve social conflicts by law. To further smooth channels of reporting social conditions and public opinion, improving regulation, arbitration, as well as dispute resolution mechanisms, implement fully the petitioners ' cases "third-party" hearings and supervising system of letters and calls, and to resolve the involved law lawsuit into the orbit of rule of law, vexatious, Twining visit visit, disturbing social order and other malicious extortion, resolutely crack down. Five, improving cadres Vitale, provide strong protection for forest development XI General Secretary stressed that the comprehensive revitalization in Northeast China, needs a high quality, solid style, cadres of the dare to play. Cadre cadres is a pledge, should want to do work and able to do good, enthusiasm is paramount. Treat party cadres, it is necessary to Strict management, and warm care, enable the broad masses of cadres work hard work, this is two parallel principles. In strict accordance with the standards of good cadres selection and appointment, the real officers, dare officers, those who want to play, good as excellent cadres at all levels of leadership in the past. At present, some leading cadres work initiative is not high, beyond political, idle, lazy governance governance, not as, slow, messy and a phenomenon still exist to varying degrees, affected and restricted economic and social development. We must mobilize the enthusiasm of cadres as an urgent task, adhere to combination of incentives and constraints, and adhere to the strict management and warm care, practical solution "for the officers not to" problem, motivate cadres and better lead the masses to an undertaking, the cadres and create the new achievement in a dare to play, good at shows as new. To identify the problem, accurate pulse
    elationship between Government and business. The "two sessions", General Secretary of "Pro", "clear" the word succinctly summarized the new relationship between Government and business, as pure politics, reshaping the political relationship specified in the direction. District leaders in handling political and business relations, engage in trading power for money, and finally stumbled, we a lesson, always keep in mind that "Pro", "clean" practicing "Pro", "clear". "Pro" is to open a sincere engagement with private enterprise to help solve practical difficulties; " Clear "is to clarify the Division of power, exercised in accordance with, private entrepreneurs with innocent purity, not abusing power for personal gain, not to engage in trading power for money. Third, in order to maintain fairness and justice. Fairness and justice is the lifeline of the rule of law, is the best development environment. Currently, lax law enforcement and the judicial sector in our region also exist to varying degrees, lawenforcement departments and individual window units power for personal gains and bribes, thick friends, relations, human cases, money cases in which seriously infringe on the legitimate rights and interests of enterprises and people. Especially some law enforcement and inspection for profit purposes, deliberately looking for corporate loopholes, found directly under the ticket does not give business improvement opportunities. We recruit a company doesn't easily, cultivating a business more difficult, never for personal gain, systematic harassment, card, last checked to check to get the enterprise collapsed. o guarantee the legitimate rights and interests. Always proceed from the overall situation of reform and development of services, fully consider the characteristics of production and management in non-public enterprises and social benefits, an accurate grasp of legal limits, protect the enthusiasm of entrepreneurs and practitioners in innovation and entrepreneurship, enhancingexpectations and confidence. To promote strict enforcement. Strengthening law enforcement procedures, improve law enforcement performance evaluation, strengthening the supervision of law enforcement, exploration and practice of risk control mechanism of law enforcement to further standardize the social security, urban management, road traffic administrative law enforcement, effectively free, extensive law-enforcement and lax enforcement of law enforcement and other issues. o uphold justice. Justice is the last line of Defense to safeguard fairness and justice, to unequivocally support the courts and procuratorates independently exercise level ... Judicial activities were rampant, must not be allowed to run, favors, money, must not be allowed to knowingly violate the miscarriage, violations of the legitimate rights and interests of the masses must not be allowed to abuse of power, to make forest mass can be felt in every judicial cases in equity and justice. Four to deepen grass-roots governance according to law（Ⅱ）式是H2O2分解的速控步骤，H2O2分解反应的反应速率方程为： －dcH2O2/dt=k´cH2O2·cKI （Ⅳ） 因为cKI近似不变，（Ⅳ）式可简化为： －dcH2O2/dt=kcH2O2 （Ⅴ） （其中k=k´cKI）。
    H2O2的催化分解反应为一级反应，对 （Ⅴ）式积分可得：ln（c/ c0）=－kt （Ⅵ） （其中c0为H2O2的初始浓度；c为反应至t时刻H2O2的浓度；k为H2O2的催化分解反应的速率常数）。
    反应的半衰期为：
    t1/2= ln2/k=0.693/k （Ⅶ）
    在等温等压条件下，在H2O2的分解反应中，氧气体积增长速率反映了H2O2的分解速率，本实验就是通过测定不同时刻放出的氧气的体积，间接地求出H2O2在相应时刻的浓度，这种方法称为物理法。
    令ⅴ∞表示H2O2全部分解放出的O2的体积；ⅴt表示反应至t时刻放出的O2的体积；则由（Ⅰ）式可看出：
    定温定压下反应产生的O2的体积ⅴt与被消耗的H2O2的浓度成正比，而ⅴ∞则与H2O2的初始浓度成正比，且两者比例系数为定值，则：c。∝ⅴ∞；c∝（ⅴ∞-ⅴt）。
    代入（Ⅵ）式可得：ln[（ⅴ∞-ⅴt）/ⅴ∞]=－kt （Ⅷ）
    →ln（ⅴ∞-ⅴt）=－kt ＋lnⅴ∞ （Ⅸ） （其中ⅴ∞可以通过外推法或加热法求得）。
     rass-roots governance according to law is an important foundation for promoting the construction of rule of law, but also the most basic development environment. Despite my good social order in General, but there are law-abiding consciousness, social order is not standard, regardless of faith, Twining visit visit and other outstanding problems. We want to actively promote the field of multi-level governance according to law, promote the continuous improvement of the social environment. To promote universal compliance. Actively foster the rule of law culture, carry out law publicity and education on honesty and trustworthiness, guide the masses and consciously abide by the law, failing to find method, problem-solving method, method of gradually changing the world, he is not looking for but someone "unspoken rules", formed all law law, abide by the good atmosphere. o strengthen the comprehensive management of public security. Deepening peace xingan construction, strongly
    against violence crime, mafia and serious criminal offences, to protect the legitimate rights and interests of citizens, legal persons, carry out criminal policy of temper justice with mercy, the maximum stimulating social vitality, and earnestly safeguard social harmony and stability. To resolve social conflicts by law. To further smooth channels of reporting social conditions and public opinion, improving regulation, arbitration, as well as dispute resolution mechanisms, implement fully the petitioners ' cases "third-party" hearings and supervising system of letters and calls, and to resolve the involved law lawsuit into the orbit of rule of law, vexatious, Twining visit visit, disturbing social order and other malicious extortion, resolutely crack down. Five, improving cadres Vitale, provide strong protection for forest development XI General Secretary stressed that the comprehensive revitalization in Northeast China, needs a high quality, solid style, cadres of the dare to play. Cadre cadres is a pledge, should want to do work and able to do good, enthusiasm is paramount. Treat party cadres, it is necessary to Strict management, and warm care, enable the broad masses of cadres work hard work, this is two parallel principles. In strict accordance with the standards of good cadres selection and appointment, the real officers, dare officers, those who want to play, good as excellent cadres at all levels of leadership in the past. At present, some leading cadres work initiative is not high, beyond political, idle, lazy governance governance, not as, slow, messy and a phenomenon still exist to varying degrees, affected and restricted economic and social development. We must mobilize the enthusiasm of cadres as an urgent task, adhere to combination of incentives and constraints, and adhere to the strict management and warm care, practical solution "for the officers not to" problem, motivate cadres and better lead the masses to an undertaking, the cadres and create the new achievement in a dare to play, good at shows as new. To identify the problem, accurate pulse2
    elationship between Government and business. The "two sessions", General Secretary of "Pro", "clear" the word succinctly summarized the new relationship between Government and business, as pure politics, reshaping the political relationship specified in the direction. District leaders in handling political and business relations, engage in trading power for money, and finally stumbled, we a lesson, always keep in mind that "Pro", "clean" practicing "Pro", "clear". "Pro" is to open a sincere engagement with private enterprise to help solve practical difficulties; " Clear "is to clarify the Division of power, exercised in accordance with, private entrepreneurs with innocent purity, not abusing power for personal gain, not to engage in trading power for money. Third, in order to maintain fairness and justice. Fairness and justice is the lifeline of the rule of law, is the best development environment. Currently, lax law enforcement and the judicial sector in our region also exist to varying degrees, lawenforcement departments and individual window units power for personal gains and bribes, thick friends, relations, human cases, money cases in which seriously infringe on the legitimate rights and interests of enterprises and people. Especially some law enforcement and inspection for profit purposes, deliberately looking for corporate loopholes, found directly under the ticket does not give business improvement opportunities. We recruit a company doesn't easily, cultivating a business more difficult, never for personal gain, systematic harassment, card, last checked to check to get the enterprise collapsed. o guarantee the legitimate rights and interests. Always proceed from the overall situation of reform and development of services, fully consider the characteristics of production and management in non-public enterprises and social benefits, an accurate grasp of legal limits, protect the enthusiasm of entrepreneurs and practitioners in innovation and entrepreneurship, enhancingexpectations and confidence. To promote strict enforcement. Strengthening law enforcement procedures, improve law enforcement performance evaluation, strengthening the supervision of law enforcement, exploration and practice of risk control mechanism of law enforcement to further standardize the social security, urban management, road traffic administrative law enforcement, effectively free, extensive law-enforcement and lax enforcement of law enforcement and other issues. o uphold justice. Justice is the last line of Defense to safeguard fairness and justice, to unequivocally support the courts and procuratorates independently exercise level ... Judicial activities were rampant, must not be allowed to run, favors, money, must not be allowed to knowingly violate the miscarriage, violations of the legitimate rights and interests of the masses must not be allowed to abuse of power, to make forest mass can be felt in every judicial cases in equity and justice. Four to deepen grass-roots governance according to law四、实验步骤
    （1）组装仪器（实验室工作人员已经装好）。
    （2）先用量筒量10mL蒸馏水和用吸量管吸取5mL 0.1mol·L-1KI溶液注入反应器的一室；再用另一支吸量管吸取5mL质量分数为2%的H2O2溶液于另一室。（注：此过程中各室的溶液都不能滴漏于另一边）。接着，盖好瓶塞，查漏。方法如下：
    水准瓶装入一定量蒸馏水，旋转三同活塞，使体系与外界相通；高举水准瓶，使量气管的水平面达到0.00mL（即ⅴ０）刻度处，然后再旋转三通活塞，使体系与外界隔绝，水准瓶放回实验台面。2min内保持不变，则表示不漏气；否则，要找出原因，排除它。
    （3）倾斜反应器，使KI溶液流入H2O2溶液中，立即开启秒表，混合溶液两室中反复转移3－4次，最后全部停留在一室，平稳且力度适中地摇匀。（注：反应器必须与量气管相通）
    （4）每隔一定时间（大约产生3.00mLO2），分别读取量气管的读数和记下对应的时间，8－12组即可。（注：每次水准瓶的液面与量气管的液面保持在同一水平方可读数）
    （5）反应器于55℃水浴中加热，至没小气泡产生（约为20min），取出反应器，冷却至原温，然后读数，至相邻读数的差值不超过0.02mL为止，记为ⅴ水浴。它与ⅴ０的差值即为ⅴ∞。
     五、实验数据记录与处理
    1、室温 26.0℃ ； 气压 100.90Kpa ； ⅴ∞ 34.80mL 关于t、1/t、ⅴt、（ⅴ∞-ⅴt）和ln（ⅴ∞-ⅴt）的数据表：
    t/s 1/t /s-1
    ⅴt/ mL （ⅴ∞-ⅴt）/ ln（ⅴ∞-ⅴt）
    mL 234 4.27×10－3 3.22 31.58 3.45 rass-roots governance according to law is an important foundation for promoting the construction of rule of law, but also the most basic development environment. Despite my good social order in General, but there are law-abiding consciousness, social order is not standard, regardless of faith, Twining visit visit and other outstanding problems. We want to actively promote the field of multi-level governance according to law, promote the continuous improvement of the social environment. To promote universal compliance. Actively foster the rule of law culture, carry out law publicity and education on honesty and trustworthiness, guide the masses and consciously abide by the law, failing to find method, problem-solving method, method of gradually changing the world, he is not looking for but someone "unspoken rules", formed all law law, abide by the good atmosphere. o strengthen the comprehensive management of public security. Deepening peace xingan construction, strongly
    against violence crime, mafia and serious criminal offences, to protect the legitimate rights and interests of citizens, legal persons, carry out criminal policy of temper justice with mercy, the maximum stimulating social vitality, and earnestly safeguard social harmony and stability. To resolve social conflicts by law. To further smooth channels of reporting social conditions and public opinion, improving regulation, arbitration, as well as dispute resolution mechanisms, implement fully the petitioners ' cases "third-party" hearings and supervising system of letters and calls, and to resolve the involved law lawsuit into the orbit of rule of law, vexatious, Twining visit visit, disturbing social order and other malicious extortion, resolutely crack down. Five, improving cadres Vitale, provide strong protection for forest development XI General Secretary stressed that the comprehensive revitalization in Northeast China, needs a high quality, solid style, cadres of the dare to play. Cadre cadres is a pledge, should want to do work and able to do good, enthusiasm is paramount. Treat party cadres, it is necessary to Strict management, and warm care, enable the broad masses of cadres work hard work, this is two parallel principles. In strict accordance with the standards of good cadres selection and appointment, the real officers, dare officers, those who want to play, good as excellent cadres at all levels of leadership in the past. At present, some leading cadres work initiative is not high, beyond political, idle, lazy governance governance, not as, slow, messy and a phenomenon still exist to varying degrees, affected and restricted economic and social development. We must mobilize the enthusiasm of cadres as an urgent task, adhere to combination of incentives and constraints, and adhere to the strict management and warm care, practical solution "for the officers not to" problem, motivate cadres and better lead the masses to an undertaking, the cadres and create the new achievement in a dare to play, good at shows as new. To identify the problem, accurate pulse3
    elationship between Government and business. The "two sessions", General Secretary of "Pro", "clear" the word succinctly summarized the new relationship between Government and business, as pure politics, reshaping the political relationship specified in the direction. District leaders in handling political and business relations, engage in trading power for money, and finally stumbled, we a lesson, always keep in mind that "Pro", "clean" practicing "Pro", "clear". "Pro" is to open a sincere engagement with private enterprise to help solve practical difficulties; " Clear "is to clarify the Division of power, exercised in accordance with, private entrepreneurs with innocent purity, not abusing power for personal gain, not to engage in trading power for money. Third, in order to maintain fairness and justice. Fairness and justice is the lifeline of the rule of law, is the best development environment. Currently, lax law enforcement and the judicial sector in our region also exist to varying degrees, lawenforcement departments and individual window units power for personal gains and bribes, thick friends, relations, human cases, money cases in which seriously infringe on the legitimate rights and interests of enterprises and people. Especially some law enforcement and inspection for profit purposes, deliberately looking for corporate loopholes, found directly under the ticket does not give business improvement opportunities. We recruit a company doesn't easily, cultivating a business more difficult, never for personal gain, systematic harassment, card, last checked to check to get the enterprise collapsed. o guarantee the legitimate rights and interests. Always proceed from the overall situation of reform and development of services, fully consider the characteristics of production and management in non-public enterprises and social benefits, an accurate grasp of legal limits, protect the enthusiasm of entrepreneurs and practitioners in innovation and entrepreneurship, enhancingexpectations and confidence. To promote strict enforcement. Strengthening law enforcement procedures, improve law enforcement performance evaluation, strengthening the supervision of law enforcement, exploration and practice of risk control mechanism of law enforcement to further standardize the social security, urban management, road traffic administrative law enforcement, effectively free, extensive law-enforcement and lax enforcement of law enforcement and other issues. o uphold justice. Justice is the last line of Defense to safeguard fairness and justice, to unequivocally support the courts and procuratorates independently exercise level ... Judicial activities were rampant, must not be allowed to run, favors, money, must not be allowed to knowingly violate the miscarriage, violations of the legitimate rights and interests of the masses must not be allowed to abuse of power, to make forest mass can be felt in every judicial cases in equity and justice. Four to deepen grass-roots governance according to law378 501 661 856 1210 1442 1743 2342 2.65×10 2.00×10－3 1.51×10－3 1.17×10－3 0.83×10－3 0.69×10－3 0.57×10－3 0.43×10－3
    －36.84 10.82 14.00 17.24 20.92 24.65 28.28 31.60 27.96 23.98 20.80 17.56 13.88 10.15 6.52 3.20 3.33 3.18 3.03 2.87 2.63 2.32 1.87 1.16 2、以ⅴt对1/t作图，外推至1/t=0，得截距即为ⅴ∞。将其与实验值ⅴ∞比较，并简单讨论之。

    讨论：
    外推可得ⅴ∞=38.20 mL
    而实验值为34.80mL；
    rass-roots governance according to law is an important foundation for promoting the construction of rule of law, but also the most basic development environment. Despite my good social order in General, but there are law-abiding consciousness, social order is not standard, regardless of faith, Twining visit visit and other outstanding problems. We want to actively promote the field of multi-level governance according to law, promote the continuous improvement of the social environment. To promote universal compliance. Actively foster the rule of law culture, carry out law publicity and education on honesty and trustworthiness, guide the masses and consciously abide by the law, failing to find method, problem-solving method, method of gradually changing the world, he is not looking for but someone "unspoken rules", formed all law law, abide by the good atmosphere. o strengthen the comprehensive management of public security. Deepening peace xingan construction, strongly
    against violence crime, mafia and serious criminal offences, to protect the legitimate rights and interests of citizens, legal persons, carry out criminal policy of temper justice with mercy, the maximum stimulating social vitality, and earnestly safeguard social harmony and stability. To resolve social conflicts by law. To further smooth channels of reporting social conditions and public opinion, improving regulation, arbitration, as well as dispute resolution mechanisms, implement fully the petitioners ' cases "third-party" hearings and supervising system of letters and calls, and to resolve the involved law lawsuit into the orbit of rule of law, vexatious, Twining visit visit, disturbing social order and other malicious extortion, resolutely crack down. Five, improving cadres Vitale, provide strong protection for forest development XI General Secretary stressed that the comprehensive revitalization in Northeast China, needs a high quality, solid style, cadres of the dare to play. Cadre cadres is a pledge, should want to do work and able to do good, enthusiasm is paramount. Treat party cadres, it is necessary to Strict management, and warm care, enable the broad masses of cadres work hard work, this is two parallel principles. In strict accordance with the standards of good cadres selection and appointment, the real officers, dare officers, those who want to play, good as excellent cadres at all levels of leadership in the past. At present, some leading cadres work initiative is not high, beyond political, idle, lazy governance governance, not as, slow, messy and a phenomenon still exist to varying degrees, affected and restricted economic and social development. We must mobilize the enthusiasm of cadres as an urgent task, adhere to combination of incentives and constraints, and adhere to the strict management and warm care, practical solution "for the officers not to" problem, motivate cadres and better lead the masses to an undertaking, the cadres and create the new achievement in a dare to play, good at shows as new. To identify the problem, accurate pulse4
    elationship between Government and business. The "two sessions", General Secretary of "Pro", "clear" the word succinctly summarized the new relationship between Government and business, as pure politics, reshaping the political relationship specified in the direction. District leaders in handling political and business relations, engage in trading power for money, and finally stumbled, we a lesson, always keep in mind that "Pro", "clean" practicing "Pro", "clear". "Pro" is to open a sincere engagement with private enterprise to help solve practical difficulties; " Clear "is to clarify the Division of power, exercised in accordance with, private entrepreneurs with innocent purity, not abusing power for personal gain, not to engage in trading power for money. Third, in order to maintain fairness and justice. Fairness and justice is the lifeline of the rule of law, is the best development environment. Currently, lax law enforcement and the judicial sector in our region also exist to varying degrees, lawenforcement departments and individual window units power for personal gains and bribes, thick friends, relations, human cases, money cases in which seriously infringe on the legitimate rights and interests of enterprises and people. Especially some law enforcement and inspection for profit purposes, deliberately looking for corporate loopholes, found directly under the ticket does not give business improvement opportunities. We recruit a company doesn't easily, cultivating a business more difficult, never for personal gain, systematic harassment, card, last checked to check to get the enterprise collapsed. o guarantee the legitimate rights and interests. Always proceed from the overall situation of reform and development of services, fully consider the characteristics of production and management in non-public enterprises and social benefits, an accurate grasp of legal limits, protect the enthusiasm of entrepreneurs and practitioners in innovation and entrepreneurship, enhancingexpectations and confidence. To promote strict enforcement. Strengthening law enforcement procedures, improve law enforcement performance evaluation, strengthening the supervision of law enforcement, exploration and practice of risk control mechanism of law enforcement to further standardize the social security, urban management, road traffic administrative law enforcement, effectively free, extensive law-enforcement and lax enforcement of law enforcement and other issues. o uphold justice. Justice is the last line of Defense to safeguard fairness and justice, to unequivocally support the courts and procuratorates independently exercise level ... Judicial activities were rampant, must not be allowed to run, favors, money, must not be allowed to knowingly violate the miscarriage, violations of the legitimate rights and interests of the masses must not be allowed to abuse of power, to make forest mass can be felt in every judicial cases in equity and justice. Four to deepen grass-roots governance according to law由此可见外推得到的值大了一点，原因应该是后面记录的三个数值相对偏大了，而导致那段线段较陡，最终导致外推时也相对向上移动了较大的一段。
    3、以ln（ⅴ∞-ⅴt）对t作图，由直线的斜率计算反应速率常数k（作图求斜率时，取氧气析出15%～85%之间的点）。

    解：
    斜率m=（3.00－2.71）÷（1000－738）
    =－0.29÷262 ≈1.10×103
    －故k=－m =1.10×103
    －4、计算H2O2的分解反应的半衰期。 解：
    t1/2=ln2/k =0.693/k
    rass-roots governance according to law is an important foundation for promoting the construction of rule of law, but also the most basic development environment. Despite my good social order in General, but there are law-abiding consciousness, social order is not standard, regardless of faith, Twining visit visit and other outstanding problems. We want to actively promote the field of multi-level governance according to law, promote the continuous improvement of the social environment. To promote universal compliance. Actively foster the rule of law culture, carry out law publicity and education on honesty and trustworthiness, guide the masses and consciously abide by the law, failing to find method, problem-solving method, method of gradually changing the world, he is not looking for but someone "unspoken rules", formed all law law, abide by the good atmosphere. o strengthen the comprehensive management of public security. Deepening peace xingan construction, strongly
    against violence crime, mafia and serious criminal offences, to protect the legitimate rights and interests of citizens, legal persons, carry out criminal policy of temper justice with mercy, the maximum stimulating social vitality, and earnestly safeguard social harmony and stability. To resolve social conflicts by law. To further smooth channels of reporting social conditions and public opinion, improving regulation, arbitration, as well as dispute resolution mechanisms, implement fully the petitioners ' cases "third-party" hearings and supervising system of letters and calls, and to resolve the involved law lawsuit into the orbit of rule of law, vexatious, Twining visit visit, disturbing social order and other malicious extortion, resolutely crack down. Five, improving cadres Vitale, provide strong protection for forest development XI General Secretary stressed that the comprehensive revitalization in Northeast China, needs a high quality, solid style, cadres of the dare to play. Cadre cadres is a pledge, should want to do work and able to do good, enthusiasm is paramount. Treat party cadres, it is necessary to Strict management, and warm care, enable the broad masses of cadres work hard work, this is two parallel principles. In strict accordance with the standards of good cadres selection and appointment, the real officers, dare officers, those who want to play, good as excellent cadres at all levels of leadership in the past. At present, some leading cadres work initiative is not high, beyond political, idle, lazy governance governance, not as, slow, messy and a phenomenon still exist to varying degrees, affected and restricted economic and social development. We must mobilize the enthusiasm of cadres as an urgent task, adhere to combination of incentives and constraints, and adhere to the strict management and warm care, practical solution "for the officers not to" problem, motivate cadres and better lead the masses to an undertaking, the cadres and create the new achievement in a dare to play, good at shows as new. To identify the problem, accurate pulse5
    elationship between Government and business. The "two sessions", General Secretary of "Pro", "clear" the word succinctly summarized the new relationship between Government and business, as pure politics, reshaping the political relationship specified in the direction. District leaders in handling political and business relations, engage in trading power for money, and finally stumbled, we a lesson, always keep in mind that "Pro", "clean" practicing "Pro", "clear". "Pro" is to open a sincere engagement with private enterprise to help solve practical difficulties; " Clear "is to clarify the Division of power, exercised in accordance with, private entrepreneurs with innocent purity, not abusing power for personal gain, not to engage in trading power for money. Third, in order to maintain fairness and justice. Fairness and justice is the lifeline of the rule of law, is the best development environment. Currently, lax law enforcement and the judicial sector in our region also exist to varying degrees, lawenforcement departments and individual window units power for personal gains and bribes, thick friends, relations, human cases, money cases in which seriously infringe on the legitimate rights and interests of enterprises and people. Especially some law enforcement and inspection for profit purposes, deliberately looking for corporate loopholes, found directly under the ticket does not give business improvement opportunities. We recruit a company doesn't easily, cultivating a business more difficult, never for personal gain, systematic harassment, card, last checked to check to get the enterprise collapsed. o guarantee the legitimate rights and interests. Always proceed from the overall situation of reform and development of services, fully consider the characteristics of production and management in non-public enterprises and social benefits, an accurate grasp of legal limits, protect the enthusiasm of entrepreneurs and practitioners in innovation and entrepreneurship, enhancingexpectations and confidence. To promote strict enforcement. Strengthening law enforcement procedures, improve law enforcement performance evaluation, strengthening the supervision of law enforcement, exploration and practice of risk control mechanism of law enforcement to further standardize the social security, urban management, road traffic administrative law enforcement, effectively free, extensive law-enforcement and lax enforcement of law enforcement and other issues. o uphold justice. Justice is the last line of Defense to safeguard fairness and justice, to unequivocally support the courts and procuratorates independently exercise level ... Judicial activities were rampant, must not be allowed to run, favors, money, must not be allowed to knowingly violate the miscarriage, violations of the legitimate rights and interests of the masses must not be allowed to abuse of power, to make forest mass can be felt in every judicial cases in equity and justice. Four to deepen grass-roots governance according to law=0.693÷（1.10×103）≈630s
    －     七、实验分析与讨论
    1、开始反应的前段时间，由于反应物混合尚为均匀，反应速率较慢，而导致时间间隔较大；随着反应的进行，反应逐渐趋于稳定，而产生的氧气的量也相对均匀了很多。但是我认为，前段反应时间间隔大的原因还可能是产生的部分氧气要用来填充胶管，而当我们以大约3mL为间隔记录数据时，实际上已反应产生比这个3mL偏大很多的氧气了，当然它相对就要花掉较多一点时间。
    2、由t —ln（ⅴ∞-ⅴt）图可以看出，反应前段时间产生约为等体积的氧气时所需的时间也大约一样；但是随着反应的进行，时间的间隔也慢慢地增大。从中可知道，反应速率不仅与温度有关系，而且与反应物的浓度有关，呈正比。
     六、思考题
    1、读取氧气体积时，量气管及水准瓶中水面处于同一水平面的作用何在？
    答：反应开始前量气管里水面所受的压力与水准瓶水面所受的压力是一样的，都是P。反应开始后，由于氧气的产生，水面所受的压力增大而降低。读取氧气体积时，使量气管及水准瓶中水面处于同一水平面，就是继续保持内外的压力相等，有利于准确读取在t时刻产生氧气的体积。
     2、用ⅴ∞数据可以计算H2O2的初始浓度c0，如用KMnO4溶液滴定H2O2溶液，求得H2O2的初始浓度c0，再由c0计算ⅴ∞是否可以？ 答：可以；
    rass-roots governance according to law is an important foundation for promoting the construction of rule of law, but also the most basic development environment. Despite my good social order in General, but there are law-abiding consciousness, social order is not standard, regardless of faith, Twining visit visit and other outstanding problems. We want to actively promote the field of multi-level governance according to law, promote the continuous improvement of the social environment. To promote universal compliance. Actively foster the rule of law culture, carry out law publicity and education on honesty and trustworthiness, guide the masses and consciously abide by the law, failing to find method, problem-solving method, method of gradually changing the world, he is not looking for but someone "unspoken rules", formed all law law, abide by the good atmosphere. o strengthen the comprehensive management of public security. Deepening peace xingan construction, strongly
    against violence crime, mafia and serious criminal offences, to protect the legitimate rights and interests of citizens, legal persons, carry out criminal policy of temper justice with mercy, the maximum stimulating social vitality, and earnestly safeguard social harmony and stability. To resolve social conflicts by law. To further smooth channels of reporting social conditions and public opinion, improving regulation, arbitration, as well as dispute resolution mechanisms, implement fully the petitioners ' cases "third-party" hearings and supervising system of letters and calls, and to resolve the involved law lawsuit into the orbit of rule of law, vexatious, Twining visit visit, disturbing social order and other malicious extortion, resolutely crack down. Five, improving cadres Vitale, provide strong protection for forest development XI General Secretary stressed that the comprehensive revitalization in Northeast China, needs a high quality, solid style, cadres of the dare to play. Cadre cadres is a pledge, should want to do work and able to do good, enthusiasm is paramount. Treat party cadres, it is necessary to Strict management, and warm care, enable the broad masses of cadres work hard work, this is two parallel principles. In strict accordance with the standards of good cadres selection and appointment, the real officers, dare officers, those who want to play, good as excellent cadres at all levels of leadership in the past. At present, some leading cadres work initiative is not high, beyond political, idle, lazy governance governance, not as, slow, messy and a phenomenon still exist to varying degrees, affected and restricted economic and social development. We must mobilize the enthusiasm of cadres as an urgent task, adhere to combination of incentives and constraints, and adhere to the strict management and warm care, practical solution "for the officers not to" problem, motivate cadres and better lead the masses to an undertaking, the cadres and create the new achievement in a dare to play, good at shows as new. To identify the problem, accurate pulse6
    elationship between Government and business. The "two sessions", General Secretary of "Pro", "clear" the word succinctly summarized the new relationship between Government and business, as pure politics, reshaping the political relationship specified in the direction. District leaders in handling political and business relations, engage in trading power for money, and finally stumbled, we a lesson, always keep in mind that "Pro", "clean" practicing "Pro", "clear". "Pro" is to open a sincere engagement with private enterprise to help solve practical difficulties; " Clear "is to clarify the Division of power, exercised in accordance with, private entrepreneurs with innocent purity, not abusing power for personal gain, not to engage in trading power for money. Third, in order to maintain fairness and justice. Fairness and justice is the lifeline of the rule of law, is the best development environment. Currently, lax law enforcement and the judicial sector in our region also exist to varying degrees, lawenforcement departments and individual window units power for personal gains and bribes, thick friends, relations, human cases, money cases in which seriously infringe on the legitimate rights and interests of enterprises and people. Especially some law enforcement and inspection for profit purposes, deliberately looking for corporate loopholes, found directly under the ticket does not give business improvement opportunities. We recruit a company doesn't easily, cultivating a business more difficult, never for personal gain, systematic harassment, card, last checked to check to get the enterprise collapsed. o guarantee the legitimate rights and interests. Always proceed from the overall situation of reform and development of services, fully consider the characteristics of production and management in non-public enterprises and social benefits, an accurate grasp of legal limits, protect the enthusiasm of entrepreneurs and practitioners in innovation and entrepreneurship, enhancingexpectations and confidence. To promote strict enforcement. Strengthening law enforcement procedures, improve law enforcement performance evaluation, strengthening the supervision of law enforcement, exploration and practice of risk control mechanism of law enforcement to further standardize the social security, urban management, road traffic administrative law enforcement, effectively free, extensive law-enforcement and lax enforcement of law enforcement and other issues. o uphold justice. Justice is the last line of Defense to safeguard fairness and justice, to unequivocally support the courts and procuratorates independently exercise level ... Judicial activities were rampant, must not be allowed to run, favors, money, must not be allowed to knowingly violate the miscarriage, violations of the legitimate rights and interests of the masses must not be allowed to abuse of power, to make forest mass can be felt in every judicial cases in equity and justice. Four to deepen grass-roots governance according to law 因为KMnO4溶液滴定H2O2溶液时，有以下关系式：2 MnO4→5 H2O2→5 O2；当知道滴定KMnO4溶液的浓度和用掉的体积以及被滴定的H2O2溶液的体积，而先求得c0；接着就可根据关系式求得氧气的物质的量；又因为此时可以把氧气当作理想气体，最后就可以根据理想气体方程：PV=nRT，求得V（即ⅴ∞）。
    －     3、H2O2和KI溶液的初始浓度对实验结果是否有影响？应根据什么条件选择它们？ 答：有影响；
    因为ⅴ∞与H2O2的初始浓度c0成正比，而k又与催化剂KI溶液的浓度成正比，所以说它们对实验结果是有影响的。
    应根据量气管的量程大小和反应的快慢程度来选择它们。

    rass-roots governance according to law is an important foundation for promoting the construction of rule of law, but also the most basic development environment. Despite my good social order in General, but there are law-abiding consciousness, social order is not standard, regardless of faith, Twining visit visit and other outstanding problems. We want to actively promote the field of multi-level governance according to law, promote the continuous improvement of the social environment. To promote universal compliance. Actively foster the rule of law culture, carry out law publicity and education on honesty and trustworthiness, guide the masses and consciously abide by the law, failing to find method, problem-solving method, method of gradually changing the world, he is not looking for but someone "unspoken rules", formed all law law, abide by the good atmosphere. o strengthen the comprehensive management of public security. Deepening peace xingan construction, strongly
    against violence crime, mafia and serious criminal offences, to protect the legitimate rights and interests of citizens, legal persons, carry out criminal policy of temper justice with mercy, the maximum stimulating social vitality, and earnestly safeguard social harmony and stability. To resolve social conflicts by law. To further smooth channels of reporting social conditions and public opinion, improving regulation, arbitration, as well as dispute resolution mechanisms, implement fully the petitioners ' cases "third-party" hearings and supervising system of letters and calls, and to resolve the involved law lawsuit into the orbit of rule of law, vexatious, Twining visit visit, disturbing social order and other malicious extortion, resolutely crack down. Five, improving cadres Vitale, provide strong protection for forest development XI General Secretary stressed that the comprehensive revitalization in Northeast China, needs a high quality, solid style, cadres of the dare to play. Cadre cadres is a pledge, should want to do work and able to do good, enthusiasm is paramount. Treat party cadres, it is necessary to Strict management, and warm care, enable the broad masses of cadres work hard work, this is two parallel principles. In strict accordance with the standards of good cadres selection and appointment, the real officers, dare officers, those who want to play, good as excellent cadres at all levels of leadership in the past. At present, some leading cadres work initiative is not high, beyond political, idle, lazy governance governance, not as, slow, messy and a phenomenon still exist to varying degrees, affected and restricted economic and social development. We must mobilize the enthusiasm of cadres as an urgent task, adhere to combination of incentives and constraints, and adhere to the strict management and warm care, practical solution "for the officers not to" problem, motivate cadres and better lead the masses to an undertaking, the cadres and create the new achievement in a dare to play, good at shows as new. To identify the problem, accurate pulse7

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